New iPhone not going through ZeroTier network

I have a Raspberry Pi setup on my network as the DNS server that is running Pi-hole for ad blocking. I also utilize for content filtering. All devices work as expected while on the network (Wi-Fi or wired) so that ads are blocked and unwanted websites and/content is blocked. While off the network, our Android phones using ZeroTier are also working as expected through my ZeroTier network. However, we just switched to iPhones and after I installed ZeroTier on my phone and connected it to my network (it is authorized and has the correct setup) ads are not being blocked and neither is it using OpenDNS for content filtering. Not at all familiar with iPhones so if I need to change some setting on my phone, any help there would be appreciated.

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